Well, try tapping sync from the yellow video out jack first, if that does not work, then get a sync cleaner and tap right into the PPU. Tapping sync from the yellow video out jack will work with some monitors, but not others.
You have the correct input pins circled on the Ultimarc RGB amp - Its VGA pins 1,2,3
I had grounding issues with the Ultimarc RGB amps, that is why I have like 3 grounds hooked up in the pics.