Okay I don't have my PS handy so I'm not sure if its AT or AT-X. Either way I'm gonna sacrafise it

I'm getting my consolized Neo up and going on a super low budget. So far this is what i've spent on the setup:
1 Slot MVS $15 (+$20 shipping)
Jamma Neo Harness $15
RGB Encoder chip FREE
Twin Arcade sticks FREE(Already had them build from a previous project)
Power Supply FREE (found in a computer by the dumpster @ my appt!)
4x MVS Carts $70 (Last Blade 1, Metal Slug 1, KOF97 and Samurai Showdown 3)
The only other costs i'm anticipating:
Parts for home-made RGB convertor (~$20 from radio schlack)
Speakers (I might be oober cheap and just wire up some old computer speakers)
Total project cost:
$120 (not too bad if ya ask me)
Back to the power supply stuff... How do I tell which line is ground and +5v and whatnot? Do i need to power it up and test w/ my multi tester? Also, what should I do with the power plugs comming off of it that I don't use? Is it ok to just snip them off and cap em?
Thanks for any help!
Big Beeeeeeeel